Few typos as per comments have already been corrected during edit of your post.
In response to your question I would like to cover related aspects.
While Using keys in collections has mainly three advantages
 - If the order changes your code will still access the correct item
 - You can directly access the item without reading through the entire
   collection
 - It can make you code more readable.
*But at the same time there are mainly three issues with using keys in
   collections
- You cannot check if the key exists 
- You cannot change the key 
- You cannot retrieve the key 
As per Pearsons article the Keys of a Collection are write-only -- there is no way to get a list of existing Keys of a Collection. Further going through quoted paragraph:-
Here, Coll is a Collection object in which we will store multiple
  CFile objects. The CollKeys Collection is used to store the keys of
  the CFile objects stored in the Coll Collection. We need this second
  Collection because the Keys of a Collection are write-only -- there is
  no way to get a list of existing Keys of a Collection. One of the
  enhancements provided by CFiles is the ability to retrieve a list of
  Keys for the Collection.
Custom Collection Classes
One way is to iterate over the members of the collection and see if there is match for what you are looking for and the other way is to catch the Item not in collection error and then set a flag to say the item does not exist.  Opinions differ on these approaches whereas some people feel it is not a good method to catch error while other section feels that it will be significantly faster than iteration for any medium to large collection.
So if we go for a method to catch error then error number we get depends on exactly what caused the error. We need a code routine to check the error.  In a simplest way it could be.
'c1 is the collection
 For i = 1 To c1.Count
     Debug.Print Err.Number, Err.Description
     If Err.Number <> 0 Then Err.Clear
 Next i
Error catching routines proposed by various professionals differ in the error number they consider important and include in their routine.Various commonly occurring error numbers associated with collection object are:-  
- Error 5Invalid procedure call or argument.This error can also occur
if an attempt is made to call a procedure that isn't valid on the
current platform. For example, some procedures may only be valid for
Microsoft Windows, or for the Macintosh, and so on.
- error 438"object doesn't support this property or method An object
is a class instance. A class instance supports some properties
defined in that class type definition and does not support this one.
- Error 457This key is already associated with an element of this
collection.You specified a key for a collection member that already
identifies another member of the collection. Choose a different key
for this member.
- Error 91Object variable or With block variable not set.There are two
steps to creating an object variable. First you must declare the
object variable. Then you must assign a valid reference to the object
variable using the Set statement. You attempted to use an object
variable that isn't yet referencing a valid object.
- Error 450Wrong number of arguments or invalid property
assignment.The number of arguments in the call to the procedure
wasn't the same as the number of required arguments expected by the
procedure.If you tried to assign a value to a read-only property,
Among the above errors error number 438 has been considered important and the other one is 5. I am incorporating a Function routine in my sample testing program which was posted by Mark Nold 7 years back in 2008 vide SO question Determining whether an object is a member of a collection in VBA with due credit to him.
Some errors like error 457 won't be allowed at the time of program test run. I tried to populated with duplicate keys data, it gave the error at the time of program testing itself as shown in the snapshot.

After removing it is showing correct output as shown in the snap shot. 

It may not be possible to get the list of keys of a collection with a vanilla collection without storing the key values in an independent array. The easiest alternative to do this is to add a reference to the Microsoft Scripting Runtime & use a more capable Dictionary instead.
I have included this approach to get the list of keys in my program.
While populating Collection it is to be ensured that the key is the second parameter and must be a unique string.
Full code of my program is.
Sub Generic_key_check()
    Dim arr As Variant
    Dim c1 As New Collection
    Dim dic As Object
    With Application
    .ScreenUpdating = False
    End With
    Set dic = CreateObject("Scripting.Dictionary")
    dic.CompareMode = vbTextCompare
    'Populate the collection
    c1.Add "sheet1", "sheet1"
    c1.Add "sheet2", "sheet2"
    c1.Add "sheet3", "sheet3"
    c1.Add "sheet4", "sheet4"
    c1.Add "sheet5", "sheet5"
    c1.Add 2014001, "Long1"
    c1.Add 2015001, "Long2"
    c1.Add 2016001, "Long3"
    c1.Add 2015002, "Long4"
    c1.Add 2016002, "Long5"
    'Populate the dictionary
    dic.Add "sheet1", "sheet1"
    dic.Add "sheet2", "sheet2"
    dic.Add "sheet3", "sheet3"
    dic.Add "sheet4", "sheet4"
    dic.Add "sheet5", "sheet5"
    dic.Add "Long1", 2014001
    dic.Add "Long2", 2015001
    dic.Add "Long3", 2016001
    dic.Add "Long4", 2015002
    dic.Add "Long5", 2016002
    ' Get a list of key items by Dictionary Method
    Dim N As Variant
    For Each N In dic.Keys
    Debug.Print "Key: " & N, "Value: " & dic.item(N)
    Next
    'Test for two types of data whether key exists or not.
    If InCollection(c1, "Long1") Then
    'If Exists("Long1", c1) Then
    Debug.Print "Good"
    Else
    ' If there is error then print out the error number and its description.
    Debug.Print Err.Number, Err.Description
    Debug.Print "Not Good"
    End If
    If InCollection(c1, "sheet2") Then
    Debug.Print "Good"
    Else
    Debug.Print Err.Number, Err.Description
    Debug.Print "Not Good"
    End If
    'Checking whether desired key has populated correctly
    Debug.Print c1("Sheet1")
    Debug.Print c1("Long3")
    'Listing out collection items to check theyexist in the collection.
    For i = 1 To c1.Count
    Debug.Print c1.item(i)
    Next i
    With Application
    .ScreenUpdating = True
    End With
    Set c1 = Nothing
End Sub
Public Function InCollection(col As Collection, key As String) As Boolean
    Dim var As Variant
    Dim errNumber As Long
    InCollection = False
    Set var = Nothing
    Err.Clear
    On Error Resume Next
    var = col.item(key)
    errNumber = CLng(Err.Number)
    On Error GoTo 0
    '5 is not in, 0 and 438 represent incollection
    If errNumber = 5 Then ' it is 5 if not in collection
    InCollection = False
    Else
    InCollection = True
    End If
End Function
Final output as per program as shown in the Immediate window has been shown in the Snapshot.
