Alright, so I've been scouring Google for a couple hours now and can't seem to find a direct answer to the problem I'm having. I have a custom window with WindowStyle = "None" and AllowsTransparency = "True" When I click on my maximize button:
    private void MaximizeButton_Click(object sender, RoutedEventArgs e)
    {
        if(this.WindowState == WindowState.Normal)
        {
            App.Current.MainWindow.WindowState = WindowState.Maximized;
        }
        else
        {
            App.Current.MainWindow.WindowState = WindowState.Normal;
        }
    }
It maximizes almost exactly the way it's supposed except it seems like there's a -6px margin on the top and left side of the window.
I don't want that white space to be there (it's only white because Google Chrome is open behind it, it's actually transparent). I need the app to maximize to fit the entire screen, excluding the taskbar. So far the only fix I've found is setting the margin of the window to Margin = "6, 6, 0, 0" when the maximize button is pressed. Here is the rest of the code for reference:
StartUp.xaml
<Window x:Class="Expense_Calculator.MainWindow"
    xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
    xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
    xmlns:d="http://schemas.microsoft.com/expression/blend/2008"
    xmlns:mc="http://schemas.openxmlformats.org/markup-compatibility/2006"
    xmlns:local="clr-namespace:Expense_Calculator"
    mc:Ignorable="d"
    Title="MainWindow" Height="350" Width="525"
    WindowStartupLocation="CenterScreen"
    WindowStyle="None"
    AllowsTransparency="True">
<Grid Name="Container" Background="#323232">
    <Grid.RowDefinitions>
        <RowDefinition Height="33"/>
        <RowDefinition Height="*"/>
    </Grid.RowDefinitions>
    <Grid>
        <DockPanel Style="{StaticResource TitleDockPanel}">
            <Label Style="{StaticResource TitleBarTitle}">App Name</Label>
            <Button Name="CloseButton" Click="CloseButton_Click" DockPanel.Dock="Right" Style="{StaticResource TitleBarButtonClose}">
                <Image Source="images/close.png"/>
            </Button>
            <Button Name="MaximizeButton" Click="MaximizeButton_Click" DockPanel.Dock="Right" Style="{StaticResource TitleBarButton}">
                <Image Source="images/maximize.png"/>
            </Button>
            <Button Name="MinimizeButton" Click="MinimizeButton_Click" DockPanel.Dock="Right" Style="{StaticResource TitleBarButton}">
                <Image Source="images/minimize.png"/>
            </Button>
        </DockPanel>
    </Grid>
    <Grid Style="{StaticResource UserArea}" Grid.Row="1">
        <Grid Name="WelcomePage">
            <Grid.RowDefinitions>
                <RowDefinition/>
                <RowDefinition/>
            </Grid.RowDefinitions>
            <Grid.ColumnDefinitions>
                <ColumnDefinition Width="Auto"/>
            </Grid.ColumnDefinitions>
            <Label Style="{StaticResource Label1}">Welcome to your Expense Calculator!</Label>
            <Button Cursor="Hand" Style="{StaticResource Button1}" Grid.Row="1">Get Started</Button>
        </Grid>
    </Grid>
</Grid>
StartUp.xaml.cs
using System.Windows;
namespace Expense_Calculator
{
    /// <summary>
    /// Interaction logic for StartUp.xaml
    /// </summary>
    public partial class MainWindow : Window
    {
        public MainWindow()
        {
            this.MaxHeight = SystemParameters.WorkArea.Height;
            this.MaxWidth = SystemParameters.WorkArea.Width;
            InitializeComponent();
        }
        private void CloseButton_Click(object sender, RoutedEventArgs e)
        {
            Application.Current.Shutdown();
        }
        private void MaximizeButton_Click(object sender, RoutedEventArgs e)
        {
            if(this.WindowState == WindowState.Normal)
            {
                App.Current.MainWindow.WindowState = WindowState.Maximized;
            }
            else
            {
                App.Current.MainWindow.WindowState = WindowState.Normal;
            }
        }
        private void MinimizeButton_Click(object sender, RoutedEventArgs e)
        {
            this.WindowState = WindowState.Minimized;
        }
    }
}
App.xaml
<Application x:Class="Expense_Calculator.App"
         xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
         xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
         xmlns:local="clr-namespace:Expense_Calculator"
         StartupUri="StartUp.xaml">
<Application.Resources>
    <!--Title Bar-->
    <Style x:Key="TitleDockPanel" TargetType="DockPanel">
        <Setter Property="VerticalAlignment" Value="Top"/>
        <Setter Property="Background" Value="#323232"/>
        <Setter Property="Height" Value="33"/>
    </Style>
    <Style x:Key="TitleBarTitle" TargetType="Label">
        <Setter Property="Foreground" Value="White"/>
        <Setter Property="VerticalAlignment" Value="Center"/>
        <Setter Property="FontSize" Value="13"/>
        <Setter Property="FontWeight" Value="DemiBold"/>
        <Setter Property="Padding" Value="10, 0"/>
    </Style>
    <Style x:Key="TitleBarButton" TargetType="Button">
        <Setter Property="Cursor" Value="Hand"/>
        <Setter Property="HorizontalAlignment" Value="Right"/>
        <Setter Property="VerticalAlignment" Value="Center"/>
        <Setter Property="Template">
            <Setter.Value>
                <ControlTemplate TargetType="Button">
                    <Border x:Name="border" Background="#323232" Height="33" Width="33">
                        <ContentPresenter VerticalAlignment="Center" HorizontalAlignment="Center" Width="15" Height="15"></ContentPresenter>
                        <VisualStateManager.VisualStateGroups>
                            <VisualStateGroup x:Name="CommonStates">
                                <VisualStateGroup.Transitions>
                                    <VisualTransition GeneratedDuration="0:0:.1"/>
                                </VisualStateGroup.Transitions>
                                <VisualState x:Name="Normal"/>
                                <VisualState x:Name="MouseOver">
                                    <Storyboard>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="Background.Color" To="#464646" Duration="0"/>
                                    </Storyboard>
                                </VisualState>
                                <VisualState x:Name="Pressed">
                                    <Storyboard>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="Background.Color" To="#3774FF" Duration="0"/>
                                    </Storyboard>
                                </VisualState>
                            </VisualStateGroup>
                        </VisualStateManager.VisualStateGroups>
                    </Border>
                </ControlTemplate>
            </Setter.Value>
        </Setter>
    </Style>
    <Style x:Key="TitleBarButtonClose" TargetType="Button">
        <Setter Property="Cursor" Value="Hand"/>
        <Setter Property="HorizontalAlignment" Value="Right"/>
        <Setter Property="VerticalAlignment" Value="Center"/>
        <Setter Property="Template">
            <Setter.Value>
                <ControlTemplate TargetType="Button">
                    <Border x:Name="border" Background="#323232" Height="33" Width="33">
                        <ContentPresenter VerticalAlignment="Center" HorizontalAlignment="Center" Width="15" Height="15"></ContentPresenter>
                        <VisualStateManager.VisualStateGroups>
                            <VisualStateGroup x:Name="CommonStates">
                                <VisualStateGroup.Transitions>
                                    <VisualTransition GeneratedDuration="0:0:.1"/>
                                </VisualStateGroup.Transitions>
                                <VisualState x:Name="Normal"/>
                                <VisualState x:Name="MouseOver">
                                    <Storyboard>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="Background.Color" To="Firebrick" Duration="0"/>
                                    </Storyboard>
                                </VisualState>
                                <VisualState x:Name="Pressed">
                                    <Storyboard>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="Background.Color" To="#781414" Duration="0"/>
                                    </Storyboard>
                                </VisualState>
                            </VisualStateGroup>
                        </VisualStateManager.VisualStateGroups>
                    </Border>
                </ControlTemplate>
            </Setter.Value>
        </Setter>
    </Style>
    <!--End - Title Bar-->
    <!--Welcome Page-->
    <Style x:Key="UserArea" TargetType="Grid">
        <Setter Property="HorizontalAlignment" Value="Center"/>
        <Setter Property="VerticalAlignment" Value="Center"/>
    </Style>
    <Style x:Key="Label1" TargetType="Label">
        <Setter Property="FontSize" Value="20"/>
        <Setter Property="Foreground" Value="White"/>
        <Setter Property="Margin" Value="0, 0, 0, 25"/>
    </Style>
    <Style x:Key="Button1" TargetType="Button">
        <Setter Property="Width" Value="Auto"/>
        <Setter Property="VerticalAlignment" Value="Center"/>
        <Setter Property="HorizontalAlignment" Value="Center"/>
        <Setter Property="Template">
            <Setter.Value>
                <ControlTemplate TargetType="Button">
                    <Border x:Name="border" Background="#323232" CornerRadius="16" BorderBrush="#505050" BorderThickness="1" Padding="15, 6">
                        <ContentPresenter x:Name="content" HorizontalAlignment="Center" VerticalAlignment="Center">
                            <TextBlock.Foreground>
                                <SolidColorBrush Color="#7D7D7D"/>
                            </TextBlock.Foreground>
                            <TextBlock.FontSize>14</TextBlock.FontSize>
                        </ContentPresenter>
                        <VisualStateManager.VisualStateGroups>
                            <VisualStateGroup x:Name="CommonStates">
                                <VisualStateGroup.Transitions>
                                    <VisualTransition GeneratedDuration="0:0:0.15"/>
                                </VisualStateGroup.Transitions>
                                <VisualState x:Name="Normal"/>
                                <VisualState x:Name="MouseOver">
                                    <Storyboard>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="Background.Color" To="#3C3C3C" Duration="0"/>
                                        <ColorAnimation Storyboard.TargetName="content" Storyboard.TargetProperty="(TextBlock.Foreground).Color" To="White" Duration="0"/>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="BorderBrush.Color" To="#C8C8C8" Duration="0"/>
                                    </Storyboard>
                                </VisualState>
                                <VisualState x:Name="Pressed">
                                    <Storyboard>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="Background.Color" To="#282828" Duration="0"/>
                                        <ColorAnimation Storyboard.TargetName="content" Storyboard.TargetProperty="(TextBlock.Foreground).Color" To="White" Duration="0"/>
                                        <ColorAnimation Storyboard.TargetName="border" Storyboard.TargetProperty="BorderBrush.Color" To="#C8C8C8" Duration="0"/>
                                    </Storyboard>
                                </VisualState>
                            </VisualStateGroup>
                        </VisualStateManager.VisualStateGroups>
                    </Border>
                    <ControlTemplate.Triggers>
                        <Trigger Property="IsEnabled" Value="False">
                            <Setter TargetName="border" Property="Opacity" Value=".25"/>
                        </Trigger>
                    </ControlTemplate.Triggers>
                </ControlTemplate>
            </Setter.Value>
        </Setter>
    </Style>
    <!--End - Welcome Page-->
</Application.Resources>
</Application>
