The variable a is a float that holds some value close to the mathematical value 2.3.
The literal 2.3 is a double that also holds some value close to the mathematical value 2.3, but because double has greater precision than float, this may be a different value from the value of a. Both float and double can only represent a finite number of values, so there are necessarily mathematical real numbers that cannot be represented exactly by either of those two types.
In the comparison a == 2.3, the left operand is promoted from float to double. This promotion is exact and preserves the value (as all promotions do), but as discussed above, that value may be a different one from that of the 2.3 literal.
To make a comparison between floats, you can use an appropriate float literal:
assert(a == 2.3f);
//             ^