here is an example of how you could do it:
% cat subject.txt                     
Studid    StudName     Asp.Net   DBMS     Unix
   1       Ani         75        62       80
   2       George      90        95       82
   3       Jake        45        30       40
   4       Dennie      89        92       90
% 
% my_var="R2D2"                       
% 
% sed "s/$/${my_var}/" subject.txt 
Studid    StudName     Asp.Net   DBMS     UnixR2D2
   1       Ani         75        62       80R2D2
   2       George      90        95       82R2D2
   3       Jake        45        30       40R2D2
   4       Dennie      89        92       90R2D2
Explanation
The tricky thing about this sed expression, is why don't I need to reinsert the $ newline in the replace part of the substitution?.
I believe this is because when sed loads each line into the pattern space it removes the newline, then after all pattern space operations, it then re-attaches a newline to the contents of the pattern space then prints the pattern space, so I guess the newline is a kind of a "freebie" here.
Then you might ask the question, how does the first $ match if the pattern space has no newline in it ? -- if I had to guess, I might say , sed just knows what you mean when you use the $ meta character, but that is just a guess.