you can use it as an simple function like:
class Validation {
    public static function emailUnique($conn, $email)
        {
            $sql = "SELECT email FROM formular WHERE email = '".$email."'";
            $emailUnique = $conn->query($sql);
            return (boolean) $emailUnique->num_rows;
        }
}
this returns a true if an entry has been found and false if not and then you can call your function in your script like this. i've used this together with bootstrap-alerts:
$errorField = "";
$labelClass = array(
 "emailUnique"=>"",
);
$email = mysqli_real_escape_string($conn, $_POST["email"]);
$errorMessages["emailUnique"] = Validation::emailUnique($conn ,$email);
$DisplayErrorForm = array();
$hasErrors = false;
$formErrorMessage = "";
foreach ($labelClass as $key=>$value) {
          if($errorMessages[$key]){
          $labelClass[$key] = "has-error";
          $hasErrors = true;
          $DisplayErrorForm["emailUnique"] = array("style" => "red", "text" => "Email is already taken");
          if($key == "emailUnique"){
               $formErrorMessage .= "<li style='" . $DisplayErrorForm["emailUnique"]["style"] . "'>" . $DisplayErrorForm["emailUnique"]["text"] . "</li>";
             }
          }
       }
if(count($DisplayErrorForm)) {
  $errorField = "<div class=\"alert alert-danger\">".
                            "<strong>Whoops!</strong> There were some problems with your input.<br><br>".
                            "<ul>".$formErrorMessage."</ul>".
                        "</div>";
        }
        if (!$hasErrors) {
        //Do the database input
and then down in your html part call the $errorField
<div>
<?php echo $errorField; ?>
</div>