This is a generator expression inside a call to the sum function.  sum just adds things up, so let's look at the generator expression:
(i+j)%k == 0 for x, i in enumerate(a) for j in a[x+1:]
The (i+j)%k == 0 part is a boolean expression.  It's either true if i+j has a remainder of 0 when dived by k or false otherwise.  As a neat little trick, the True value has a numeric value of 1 in python, and False has a numeric value of 0.  So this is basically just counting.
for x, i in enumerate(a) for j in a[x+1:]
This is essentially a nested for loop.  
for x, i in enumerate(a):
    for j in a[x+1:]:
enumerate is a function that yields items from an iterable paired with their index, so [a, b, c] becomes [(0, a), (1, b), (2, c)]
Stick it all together, and this code calculates the number of pairs of elements in a list such that their sum is divisible byk