If I have got this right I think there are a couple of things I would change which may help you:
- Use Using. This will dispose of the SQL objects once finished with.
- Use SqlParameters. This will help with filtering your data.
- Remove the use of SqlDataAdapter. In this case I don't feel it's needed.
- The use of IIf. I will be usingIfwhich has replacedIIf.
With these in mind I would look at something like this:
Dim fromValue As Decimal = 0D
Dim toValue As Decimal = 0D
If Decimal.TryParse(TextBox1.Text, fromValue) AndAlso Decimal.TryParse(TextBox1.Text, toValue) Then
    Dim dt As New DataTable
    Using conn As SqlConnection = SQLConn,
          cmd As New SqlCommand("SELECT [Equivalent Value] FROM tblSSS WHERE [From] >= @From AND [To] <= @To", conn)
        cmd.Parameters.Add(New SqlParameter With {.ParameterName = "@From", .SqlDbType = SqlDbType.Decimal, .Value = fromValue})
        cmd.Parameters.Add(New SqlParameter With {.ParameterName = "@To", .SqlDbType = SqlDbType.Decimal, .Value = toValue})
        conn.Open()
        dt.Load(cmd.ExecuteReader)
    End Using
    If dt.Rows.Count = 1 Then
        TextBox2.Text = If(IsDBNull(dt.Rows(0).Item("Equivalent Value")), "0", dt.Rows(0).Item("Equivalent Value").ToString)
    End If
End If
Note the use of Decimal.TryParse:
Converts the string representation of a number to its Decimal equivalent. A return value indicates whether the conversion succeeded or failed.
This is an assumption that the From and To fields in your database are Decimal.
Now to explain the difference between IIf and If. IIf executes each portion of the statement even if it's true whilst If executes only one portion. I won't go into detail as many others on here have done that already. Have a look at this answer.
As per Andrew Morton's comment and more in line with what the OP attempted here is a solution that uses ExecuteScaler.
ExecuteScaler executes the query, and returns the first column of the first row in the result set returned by the query. Additional columns or rows are ignored.
With this in mind:
'I reset the value of TextBox2.Text. You may not want to.
TextBox2.Text = ""
Dim fromValue As Decimal = 0D
Dim toValue As Decimal = 0D
If Decimal.TryParse(TextBox1.Text, fromValue) AndAlso Decimal.TryParse(TextBox1.Text, toValue) Then
    Using conn As SqlConnection = SQLConn,
          cmd As New SqlCommand("SELECT [Equivalent Value] FROM tblSSS WHERE [From] >= @From AND [To] <= @To", conn)
        cmd.Parameters.Add(New SqlParameter With {.ParameterName = "@From", .SqlDbType = SqlDbType.Decimal, .Value = fromValue})
        cmd.Parameters.Add(New SqlParameter With {.ParameterName = "@To", .SqlDbType = SqlDbType.Decimal, .Value = toValue})
        conn.Open()
        Try
            TextBox2.Text = cmd.ExecuteScalar().ToString()
        Catch ex As Exception
        End Try
    End Using
End If
I have used the example on the ExecuteScaler MSDN documentation. You might want to look into handling the exception on the Try Catch a little better and not letting it go to waste.
You may want to place this code on the TextBox1.Leave method or maybe on a Button.Click method. That's totally up to you.
There may a few changes you may need to make however I think this will give you a few ideas on how to move ahead with your code.