In python, the [a:b:c] syntax creates a new list. That is,
list = [1,2,3]
print(list[:])
is going to print a list, not a value.
Therefore, when you say list[:][0] you are making a copy of the original list (list[:]) and then accessing item 0 within it.
Of course you know, item 0 of the original list (list[0]) is another list.
I think you want:
[sl[0] for sl in list]
Elaboration:
This is called a "comprehension." It is a compact special syntax for generating lists, dicts, and tuples by processing or filtering other iterables. Basically {..}, [..], and (..) with an expression inside involving a for and optionally an if. Naturally, you can have multiples (like [x for x in y for y in z]) of the for, and multiples of the if. 
In your case, it's pretty obvious you want a list. So []. You want to make the list by taking the first item from each sublist. So [sl[0] for sl in list].
Here's a more-detailed article: http://carlgroner.me/Python/2011/11/09/An-Introduction-to-List-Comprehensions-in-Python.html