I have a ul element and 5  child <li>.
<ul>
  <li></li>
  <li></li>
  <li></li>
  <li></li>
  <li></li>
</ul>
The <ul> has a display: flex property. 
I tried using the calc property on the <li> to evenly size my list items:
calc:(100% / 5);
This gives the desired result and evenly sizes the 5 <li> blocks
Now I added borders to the right side of all, but the last child <li> element. So I reduced the total width of all the borders combined from the total width of the <ul>.
calc:((100% - 8px) / 5);
This also worked properly and evenly sized the <li> blocks with the borders.
ul {
  width: 600px;
  height: 300px;
  margin: 0;
  padding: 0;
  display: flex;
  background: red;
}
li {
  list-style: none;
  display: block;
  width: calc((100% - 0.8px) / 5);
  height: 100%;
  border-right: 0.2px solid black;
  background: blue;
}
li:last-child {
  border-right: none;
}<ul>
  <li></li>
  <li></li>
  <li></li>
  <li></li>
  <li></li>
</ul>Now I tried to set the border width in viewport unit vw instead of px but it gives a different result.
ul {
  width: 600px;
  height: 300px;
  margin: 0;
  padding: 0;
  display: flex;
  background: red;
}
li {
  list-style: none;
  display: block;
  width: calc((100% - 0.8vw) / 5);
  height: 100%;
  border-right: 0.2vw solid black;
  background: blue;
}
li:last-child {
  border-right: none;
}<ul>
  <li></li>
  <li></li>
  <li></li>
  <li></li>
  <li></li>
</ul>As you can see from the snippet above, there is a little bit of space to the right. This becomes bigger with a wider viewport (try viewing the snippet full page). So I think the problem lies with the vw units and flexbox here. 
So what is the cause of this error?
EDIT:
From the provided answers and comments, I have seen there are other and more proper approches to achieve what I was trying to do.  I appreciate those answers but those are not the answers to my question. Since calc is showing an error in this case, most likely it will cause more problems when I try to use calc and viewport units in other cases (not just borders). So I need to know the reason and "calc" fix.
 
     
    