One of the way would be to do stat() and check on errno.
A sample code would look look this:
#include <sys/stat.h>
using namespace std;
// some lines of code...
int fileExist(const string &filePath) {
    struct stat statBuff;
    if (stat(filePath.c_str(), &statBuff) < 0) {
        if (errno == ENOENT) return -ENOENT;
    }
    else
        // do stuff with file
}
This works irrespective of the stream. If you still prefer to check using ofstream just check using is_open().
Example:  
ofstream fp.open("<path-to-file>", ofstream::out);
if (!fp.is_open()) 
    return false;
else 
    // do stuff with file
Hope this helps.
Thanks!