It's the comma operator, also known as the "evaluate and forget" operator. The effect of a, b is:
- Evaluate
a, including any side effects
- Discard its value (i.e. do nothing with it)
- Evaluate
b
- Use the result of
b as the result of the entire expression a, b
The author of the loop wanted to express the following:
Read command from cin, and then enter the loop body unless command is equal to "END"
However, they would have been better off using && instead of , here, because cin >> command can fail (i.e. if the end of input is reached before the word END is found). In such case, the condition with , will not do what was intended (it will likely loop forever, as command will never receive the value END), while the condition with && would do the right thing (terminate).