I have a data frame containing 3 columns and a large number of rows
     A     B     C     D     E
aa   hi    43    21    22    45
ab   helo  44    65    86    94
ac   hola  42    71    91    44
ad   hi    12    79    45    12
ae   hey   81    14    34    42
af   hi    21    45    12    02
ag   hola  04    12    39    65
I want to remove all multiple occurrences in column A, keeping the first row and eliminate the rest, so I expect a data frame as follows
     A     B     C     D     E
aa   hi    43    21    22    45
ab   helo  44    65    86    94
ac   hola  42    71    91    44
ae   hey   81    14    34    42