I know following error
ValueError: The truth value of a Series is ambiguous. Use a.empty, a.bool(), a.item(), a.any() or a.all().
has been asked a long time ago.
However, I am trying to create a basic function and return a new column with df['busy'] with 1 or 0. My function looks like this,
def hour_bus(df):
    if df[(df['hour'] >= '14:00:00') & (df['hour'] <= '23:00:00')&\
             (df['week_day'] != 'Saturday') & (df['week_day'] != 'Sunday')]:
         return df['busy'] == 1
     else:
         return df['busy'] == 0 
I can execute the function, but when I call it with the DataFrame, I get the error mentioned above. I followed the following thread and another thread to create that function.  I used & instead of and in my if clause. 
Anyhow, when I do the following, I get my desired output.
df['busy'] = np.where((df['hour'] >= '14:00:00') & (df['hour'] <= '23:00:00') & \
                        (df['week_day'] != 'Saturday') & (df['week_day'] != 'Sunday'),'1','0')
Any ideas on what mistake am I making in my hour_bus function?
 
    