file A
phy     44  
chem    46 
maths   44  
biol    42
his     38
comm    40
file B
        RaK   John
Phy    45   23
chem    43  45
maths   41   90
His     38   25
Comm    48  12
geo     49   42
Expected output
            RaK
phy    44   45
chem    46  43
maths   44  41
biol    42  0
his     38  38
comm    40  48
I need somthing like join(-a1 a,b) but in python which should be able to handle huge amount of data
 
    