If I write code using comma operator like this:
int i;
i = 5, i++, i++;
does it invoke undefined behavior?
If I write code using comma operator like this:
int i;
i = 5, i++, i++;
does it invoke undefined behavior?
 
    
     
    
    No. It will not invoke undefined behavior as there is a sequence point between evaluation of left and right operands of comma operators.
= has higher precedence than that of , operator and therefore 5 will bind to = as   
(i = 5), i++, i++;
Since operands of comma operator guaranteed to evaluates from left to right, i = 5 will be evaluated first and i will be assigned 5, then the second expression i++ will be evaluated and i will be 6 and finally the third expression will increment i to 7.  
The above statement is equivalent to
i = 5;
i++;
i++;
 
    
    does it invoke undefined behavior?
No, because of both the sequence points the comma operator introduces and operator precedence. A sequence point assures that all side effects of the previous evaluations have been performed before evaluating the following expressions.
Sequence points and operator precende assure that in the i = 5, i++, i++; statement, i will be initialized before evaluating any of the i++ expressions.
The statement:
i = 5, i++, i++;
is, considering operator precedence, equivalent to:
((i = 5), i++), i++;
So, first (i = 5) is evaluated. After its side effects are over (i.e.: after i is initialized to 5), the following expression, i++ is evaluated. Again, after the side effect this last expression introduces is over (i.e.: i is increased by one), the last expression, i++, is evaluated. 
 
    
    No, does not invoke undefined behavior because the comma operator is a sequence point. i is assigned a value of 5 and then incremented twice.
