div() functions in standard C
I think you should look at the div() functions from <stdlib.h>. (They are standard C functions and are defined in all versions of the standard, despite the link to the POSIX specification.)
The C11 standard §7.22.6.2 specifies:
The div … functions compute numer / denom and numer % denom in a single operation.
Note that C11 specifies integer division in §6.5.5 (and C99 was similar):
When integers are divided, the result of the / operator is the algebraic quotient with any fractional part discarded.105)
105) This is often called "truncation toward zero".
but C90 (§6.3.5) was more flexible yet less useful:
When integers are divided and the division is inexact. if both operands are positive the result of the / operator is the largest integer less than the algebraic quotient and the result of the % operator is positive. If either operand is negative, whether the result of the / operator is the largest integer less than or equal to the algebraic quotient or the smallest integer greater than or equal to the algebraic quotient is implementation-defined, as is the sign of the result of the % operator.
floor_div()
The computational code for the requested floor_div() using div() is neat and tidy.
int floor_div(int a, int b)
{
    assert(b != 0);
    div_t r = div(a, b);
    if (r.rem != 0 && ((a < 0) ^ (b < 0)))
        r.quot--;
    return r.quot;
}
Test code
The print formatting in the code below is tailored rather precisely to the sample data. (It would be better, but more expansive, to use %4d and %-4d throughout).  This code prints lines of length 89 characters plus newline; the more general layout would print lines of length 109.  Neither avoids the horizontal scroll bar on SO.
#include <assert.h>
#include <stdio.h>
#include <stdlib.h>
static int floor_div(int a, int b)
{
    assert(b != 0);
    div_t r = div(a, b);
    if (r.rem != 0 && ((a < 0) ^ (b < 0)))
        r.quot--;
    return r.quot;
}
static void test_floor_div(int n, int d)
{
    assert(d != 0);
    printf(   "%3d/%-2d = %-3d (%3d)", +n, +d, floor_div(+n, +d), +n / +d);
    printf(";  %3d/%-3d = %-4d (%4d)", +n, -d, floor_div(+n, -d), +n / -d);
    if (n != 0)
    {
        printf(";  %4d/%-2d = %-4d (%4d)", -n, +d, floor_div(-n, +d), -n / +d);
        printf(";  %4d/%-3d = %-3d (%3d)", -n, -d, floor_div(-n, -d), -n / -d);
    }
    putchar('\n');
}
int main(void)
{
    int numerators[] = { 0, 1, 2, 4, 9, 23, 291 };
    enum { NUM_NUMERATORS = sizeof(numerators) / sizeof(numerators[0]) };
    int denominators[] = { 1, 2, 3, 6, 17, 23 };
    enum { NUM_DENOMINATORS = sizeof(denominators) / sizeof(denominators[0]) };
    for (int i = 0; i < NUM_NUMERATORS; i++)
    {
        for (int j = 0; j < NUM_DENOMINATORS; j++)
            test_floor_div(numerators[i], denominators[j]);
        putchar('\n');
    }
    return 0;
}
Test output
  0/1  = 0   (  0);    0/-1  = 0    (   0)
  0/2  = 0   (  0);    0/-2  = 0    (   0)
  0/3  = 0   (  0);    0/-3  = 0    (   0)
  0/6  = 0   (  0);    0/-6  = 0    (   0)
  0/17 = 0   (  0);    0/-17 = 0    (   0)
  0/23 = 0   (  0);    0/-23 = 0    (   0)
  1/1  = 1   (  1);    1/-1  = -1   (  -1);    -1/1  = -1   (  -1);    -1/-1  = 1   (  1)
  1/2  = 0   (  0);    1/-2  = -1   (   0);    -1/2  = -1   (   0);    -1/-2  = 0   (  0)
  1/3  = 0   (  0);    1/-3  = -1   (   0);    -1/3  = -1   (   0);    -1/-3  = 0   (  0)
  1/6  = 0   (  0);    1/-6  = -1   (   0);    -1/6  = -1   (   0);    -1/-6  = 0   (  0)
  1/17 = 0   (  0);    1/-17 = -1   (   0);    -1/17 = -1   (   0);    -1/-17 = 0   (  0)
  1/23 = 0   (  0);    1/-23 = -1   (   0);    -1/23 = -1   (   0);    -1/-23 = 0   (  0)
  2/1  = 2   (  2);    2/-1  = -2   (  -2);    -2/1  = -2   (  -2);    -2/-1  = 2   (  2)
  2/2  = 1   (  1);    2/-2  = -1   (  -1);    -2/2  = -1   (  -1);    -2/-2  = 1   (  1)
  2/3  = 0   (  0);    2/-3  = -1   (   0);    -2/3  = -1   (   0);    -2/-3  = 0   (  0)
  2/6  = 0   (  0);    2/-6  = -1   (   0);    -2/6  = -1   (   0);    -2/-6  = 0   (  0)
  2/17 = 0   (  0);    2/-17 = -1   (   0);    -2/17 = -1   (   0);    -2/-17 = 0   (  0)
  2/23 = 0   (  0);    2/-23 = -1   (   0);    -2/23 = -1   (   0);    -2/-23 = 0   (  0)
  4/1  = 4   (  4);    4/-1  = -4   (  -4);    -4/1  = -4   (  -4);    -4/-1  = 4   (  4)
  4/2  = 2   (  2);    4/-2  = -2   (  -2);    -4/2  = -2   (  -2);    -4/-2  = 2   (  2)
  4/3  = 1   (  1);    4/-3  = -2   (  -1);    -4/3  = -2   (  -1);    -4/-3  = 1   (  1)
  4/6  = 0   (  0);    4/-6  = -1   (   0);    -4/6  = -1   (   0);    -4/-6  = 0   (  0)
  4/17 = 0   (  0);    4/-17 = -1   (   0);    -4/17 = -1   (   0);    -4/-17 = 0   (  0)
  4/23 = 0   (  0);    4/-23 = -1   (   0);    -4/23 = -1   (   0);    -4/-23 = 0   (  0)
  9/1  = 9   (  9);    9/-1  = -9   (  -9);    -9/1  = -9   (  -9);    -9/-1  = 9   (  9)
  9/2  = 4   (  4);    9/-2  = -5   (  -4);    -9/2  = -5   (  -4);    -9/-2  = 4   (  4)
  9/3  = 3   (  3);    9/-3  = -3   (  -3);    -9/3  = -3   (  -3);    -9/-3  = 3   (  3)
  9/6  = 1   (  1);    9/-6  = -2   (  -1);    -9/6  = -2   (  -1);    -9/-6  = 1   (  1)
  9/17 = 0   (  0);    9/-17 = -1   (   0);    -9/17 = -1   (   0);    -9/-17 = 0   (  0)
  9/23 = 0   (  0);    9/-23 = -1   (   0);    -9/23 = -1   (   0);    -9/-23 = 0   (  0)
 23/1  = 23  ( 23);   23/-1  = -23  ( -23);   -23/1  = -23  ( -23);   -23/-1  = 23  ( 23)
 23/2  = 11  ( 11);   23/-2  = -12  ( -11);   -23/2  = -12  ( -11);   -23/-2  = 11  ( 11)
 23/3  = 7   (  7);   23/-3  = -8   (  -7);   -23/3  = -8   (  -7);   -23/-3  = 7   (  7)
 23/6  = 3   (  3);   23/-6  = -4   (  -3);   -23/6  = -4   (  -3);   -23/-6  = 3   (  3)
 23/17 = 1   (  1);   23/-17 = -2   (  -1);   -23/17 = -2   (  -1);   -23/-17 = 1   (  1)
 23/23 = 1   (  1);   23/-23 = -1   (  -1);   -23/23 = -1   (  -1);   -23/-23 = 1   (  1)
291/1  = 291 (291);  291/-1  = -291 (-291);  -291/1  = -291 (-291);  -291/-1  = 291 (291)
291/2  = 145 (145);  291/-2  = -146 (-145);  -291/2  = -146 (-145);  -291/-2  = 145 (145)
291/3  = 97  ( 97);  291/-3  = -97  ( -97);  -291/3  = -97  ( -97);  -291/-3  = 97  ( 97)
291/6  = 48  ( 48);  291/-6  = -49  ( -48);  -291/6  = -49  ( -48);  -291/-6  = 48  ( 48)
291/17 = 17  ( 17);  291/-17 = -18  ( -17);  -291/17 = -18  ( -17);  -291/-17 = 17  ( 17)
291/23 = 12  ( 12);  291/-23 = -13  ( -12);  -291/23 = -13  ( -12);  -291/-23 = 12  ( 12)