See these transformation equations from Wikipedia. But note since you want "elevation" or "vertical-axis" to be zero on the xy-plane, you need to make the changes noted after "if theta measures elevation from the reference plane instead of inclination from the zenith".
First, find a vector from the NPC to the player to get the values x, y, z, where x is positive to the East, y is positive to the North, and z is positive upward.
Then you have:
float r = sqrtf(x*x+y*y+z*z);
float theta = asinf(z/r);
float phi = atan2f(x,y);
Or you might get better precision from replacing the first declaration with
float r = hypotf(hypotf(x,y), z);
Note acosf and atan2f return radians, not degrees. If you need degrees, start with:
theta *= 180./M_PI;
and theta is now your "vertical axis" angle.
Also, Wikipedia's phi = arctan(y/x) assumes an azimuth of zero at the positive x-axis and pi/2 at the positive y-axis. Since you want an azimuth of zero at the North direction and 90 at the East direction, I've switched to atan2f(x,y) (instead of the more common atan2f(y,x)). Also, atan2f returns a value from -pi to pi inclusive, but you want strictly positive values. So:
if (phi < 0) {
phi += 2*M_PI;
}
phi *= 180./M_PI;
and now phi is your desired "horizontal-axis" angle.