I use PHPMailer, along with Apache and PHP, locally. When I test my SSL config and my cacerts I get
default_cert_file = C:\Program Files\Common Files\SSL/cert.pem
default_cert_file_env = SSL_CERT_FILE
default_cert_dir = C:\Program Files\Common Files\SSL/certs
default_cert_dir_env = SSL_CERT_DIR
default_private_dir = C:\Program Files\Common Files\SSL/private
default_default_cert_area = C:\Program Files\Common Files\SSL
ini_cafile = 
ini_capath = 
and then, I do
 var_dump(fsockopen("smtp.gmail.com", 465, $errno, $errstr, 3.0));
 var_dump($errno);
 var_dump($errstr);
and I get
fsockopen resource(2) of type (stream) int(0) string(0) "" 
In my php.ini I have curl.cainfo = C:/php/cacert.pem in the curl part and it works. 
But when I try to use PHPMailer to send a mail from localhost, I keep getting
SSL operation failed with code 1. OpenSSL Error messages:error:1416F086:SSL routines:tls_process_server_certificate:certificate verify failed 
Failed to enable crypto
unable to connect to ssl://smtp.gmail.com:465 (Unknown error)
I also went to the account used in the SMTP, in https://accounts.google.com/DisplayUnlockCaptcha and enable it. And to https://myaccount.google.com/lesssecureapps?pli=1 and enabled less secured apps. 
I guess this is an SSL error and not a PHPMailer. Frankly, I am confused dont know how to fix it. Excuse my ignorance, any help on whats is going wrong and how to fix it , would be great.
PS, this my php file that sends the mail. Thank you
<?php
use PHPMailer\PHPMailer\PHPMailer;
use PHPMailer\PHPMailer\Exception;    
require 'C:/php/PHPMailer/src/Exception.php';
require 'C:/php/PHPMailer/src/PHPMailer.php';
require 'C:/php/PHPMailer/src/SMTP.php';
$mail = new PHPMailer(true);                             
try {
    $mail->SMTPDebug = 3;
    $mail->isSMTP();                                      
    $mail->Host = 'smtp.gmail.com'; 
    $mail->SMTPAuth = true;                               
    $mail->Username = 'slevin@gmail.com';                 
    $mail->Password = 'secret';                           
    $mail->SMTPSecure = 'ssl';                            
    $mail->Port = 465;                                    
    //Recipients
    $mail->setFrom('slevin@gmail.com');
    $mail->addAddress('jacob@gmail.com');     
    //Content
    $mail->isHTML(true);                                 
    $mail->Subject = 'subject';
    $mail->Body    = 'HTML message body <b>in bold!</b>';
    $mail->AltBody = 'body in plain text';
    $mail->send();
    echo 'Message has been sent';
} catch (Exception $e) {
    echo 'Message could not be sent.';
    echo 'Mailer Error: ' . $mail->ErrorInfo;
}            
?>
Update
When I try with $mail->SMTPSecure = 'ssl'; and $mail->Port = 465; I get 
2017-10-01 13:04:25 Connection: opening to ssl://smtp.gmail.com:465, timeout=300, options=array()
2017-10-01 13:04:26 Connection failed. Error #2: stream_socket_client(): SSL operation failed with code 1. OpenSSL Error messages:error:1416F086:SSL routines:tls_process_server_certificate:certificate verify failed [C:\php\PHPMailer\src\SMTP.php line 324]
2017-10-01 13:04:26 Connection failed. Error #2: stream_socket_client(): Failed to enable crypto [C:\php\PHPMailer\src\SMTP.php line 324]
2017-10-01 13:04:26 Connection failed. Error #2: stream_socket_client(): unable to connect to ssl://smtp.gmail.com:465 (Unknown error) [C:\php\PHPMailer\src\SMTP.php line 324]
2017-10-01 13:04:26 SMTP ERROR: Failed to connect to server: (0)
SMTP connect() failed. https://github.com/PHPMailer/PHPMailer/wiki/Troubleshooting
Message could not be sent.Mailer Error: SMTP connect() failed. https://github.com/PHPMailer/PHPMailer/wiki/Troubleshooting
When I try with $mail->SMTPSecure = 'tls'; and $mail->Port = 587; I get 
2017-10-01 13:07:20 Connection: opening to smtp.gmail.com:587, timeout=300, options=array()
2017-10-01 13:07:21 Connection: opened
2017-10-01 13:07:21 SERVER -> CLIENT: 220 smtp.gmail.com ESMTP l4sm5217189wrb.74 - gsmtp
2017-10-01 13:07:21 CLIENT -> SERVER: EHLO localhost
2017-10-01 13:07:21 SERVER -> CLIENT: 250-smtp.gmail.com at your service, [85.75.196.114]250-SIZE 35882577250-8BITMIME250-STARTTLS250-ENHANCEDSTATUSCODES250-PIPELINING250 SMTPUTF8
2017-10-01 13:07:21 CLIENT -> SERVER: STARTTLS
2017-10-01 13:07:21 SERVER -> CLIENT: 220 2.0.0 Ready to start TLS
2017-10-01 13:07:21 Connection failed. Error #2: stream_socket_enable_crypto(): SSL operation failed with code 1. OpenSSL Error messages:error:1416F086:SSL routines:tls_process_server_certificate:certificate verify failed [C:\php\PHPMailer\src\SMTP.php line 403]
SMTP Error: Could not connect to SMTP host.
2017-10-01 13:07:21 CLIENT -> SERVER: QUIT
2017-10-01 13:07:21 SERVER -> CLIENT: 
2017-10-01 13:07:21 SMTP ERROR: QUIT command failed: 
2017-10-01 13:07:21 Connection: closed
SMTP Error: Could not connect to SMTP host.
Message could not be sent.Mailer Error: SMTP Error: Could not connect to SMTP host.
 
     
     
     
    