You can check the actual pixel ratio with -webkit-min-device-pixel-ratio in media queries. For example, the Galaxy S4 and onwards has a -webkit-device-pixel-ratio of 4, whereas the S3 only has a ratio of 3. Targeting based on this will allow you to present different mobile views per device.
Here's an example that will only target an S3:
@media screen 
  and (device-width: 320px) 
  and (device-height: 640px) 
  and (-webkit-device-pixel-ratio: 2) {
}
You can find a complete list of devices and their relevant media queries on this CSS Tricks page.
Remember to include a META tag in your <head> section that allows for scaling:
<meta content="width=device-width, initial-scale=1.0, maximum-scale=1.0, user-scalable=0" name="viewport" /> 
The actual redirection you're talking about can't be handled via CSS, and is typically handled via JavaScript.
This can be (crudely) done simply with a check against window.screen.width:
if (window.screen.width < 1000) {
  window.location = 'm.mysite.com';
}
Though it's much safer to check against the user agent:
var isMobile = function() {
  console.log("Navigator: " + navigator.userAgent);
  return /(iphone|ipod|ipad|android|blackberry|windows ce|palm|symbian)/i.test(navigator.userAgent);
};
Hope this helps! :)