This solution contains 2 queues:
 1. main_q - stores the input numbers.
 2. min_q - stores the min numbers by certain rules that we'll described (appear in functions MainQ.enqueue(x), MainQ.dequeue(), MainQ.get_min()).
Here's the code in Python. Queue is implemented using a List.
The main idea lies in the MainQ.enqueue(x), MainQ.dequeue(), MainQ.get_min()  functions.
One key assumption is that emptying a queue takes o(0). 
A test is provided at the end.
import numbers
class EmptyQueueException(Exception):
    pass
class BaseQ():
    def __init__(self):
        self.l = list()
    def enqueue(self, x):
        assert isinstance(x, numbers.Number)
        self.l.append(x)
    def dequeue(self):
        return self.l.pop(0)
    def peek_first(self):
        return self.l[0]
    def peek_last(self):
        return self.l[len(self.l)-1]
    def empty(self):
        return self.l==None or len(self.l)==0
    def clear(self):
        self.l=[]
class MainQ(BaseQ):
    def __init__(self, min_q):
        super().__init__()
        self.min_q = min_q
    def enqueue(self, x):
        super().enqueue(x)
        if self.min_q.empty():
            self.min_q.enqueue(x)
        elif x > self.min_q.peek_last():
            self.min_q.enqueue(x)
        else: # x <= self.min_q.peek_last():
            self.min_q.clear()
            self.min_q.enqueue(x)
    def dequeue(self):
        if self.empty():
            raise EmptyQueueException("Queue is empty")
        x = super().dequeue()
        if x == self.min_q.peek_first():
            self.min_q.dequeue()
        return x
    def get_min(self):
        if self.empty():
            raise EmptyQueueException("Queue is empty, NO minimum")
        return self.min_q.peek_first()
INPUT_NUMS = (("+", 5), ("+", 10), ("+", 3), ("+", 6), ("+", 1), ("+", 2), ("+", 4), ("+", -4), ("+", 100), ("+", -40),
              ("-",None), ("-",None), ("-",None), ("+",-400), ("+",90), ("-",None),
              ("-",None), ("-",None), ("-",None), ("-",None), ("-",None), ("-",None), ("-",None), ("-",None))
if __name__ == '__main__':
    min_q = BaseQ()
    main_q = MainQ(min_q)
    try:
        for operator, i in INPUT_NUMS:
            if operator=="+":
                main_q.enqueue(i)
                print("Added {} ; Min is: {}".format(i,main_q.get_min()))
                print("main_q = {}".format(main_q.l))
                print("min_q = {}".format(main_q.min_q.l))
                print("==========")
            else:
                x = main_q.dequeue()
                print("Removed {} ; Min is: {}".format(x,main_q.get_min()))
                print("main_q = {}".format(main_q.l))
                print("min_q = {}".format(main_q.min_q.l))
                print("==========")
    except Exception as e:
        print("exception: {}".format(e))
The output of the above test is:
"C:\Program Files\Python35\python.exe" C:/dev/python/py3_pocs/proj1/priority_queue.py
Added 5 ; Min is: 5
main_q = [5]
min_q = [5]
==========
Added 10 ; Min is: 5
main_q = [5, 10]
min_q = [5, 10]
==========
Added 3 ; Min is: 3
main_q = [5, 10, 3]
min_q = [3]
==========
Added 6 ; Min is: 3
main_q = [5, 10, 3, 6]
min_q = [3, 6]
==========
Added 1 ; Min is: 1
main_q = [5, 10, 3, 6, 1]
min_q = [1]
==========
Added 2 ; Min is: 1
main_q = [5, 10, 3, 6, 1, 2]
min_q = [1, 2]
==========
Added 4 ; Min is: 1
main_q = [5, 10, 3, 6, 1, 2, 4]
min_q = [1, 2, 4]
==========
Added -4 ; Min is: -4
main_q = [5, 10, 3, 6, 1, 2, 4, -4]
min_q = [-4]
==========
Added 100 ; Min is: -4
main_q = [5, 10, 3, 6, 1, 2, 4, -4, 100]
min_q = [-4, 100]
==========
Added -40 ; Min is: -40
main_q = [5, 10, 3, 6, 1, 2, 4, -4, 100, -40]
min_q = [-40]
==========
Removed 5 ; Min is: -40
main_q = [10, 3, 6, 1, 2, 4, -4, 100, -40]
min_q = [-40]
==========
Removed 10 ; Min is: -40
main_q = [3, 6, 1, 2, 4, -4, 100, -40]
min_q = [-40]
==========
Removed 3 ; Min is: -40
main_q = [6, 1, 2, 4, -4, 100, -40]
min_q = [-40]
==========
Added -400 ; Min is: -400
main_q = [6, 1, 2, 4, -4, 100, -40, -400]
min_q = [-400]
==========
Added 90 ; Min is: -400
main_q = [6, 1, 2, 4, -4, 100, -40, -400, 90]
min_q = [-400, 90]
==========
Removed 6 ; Min is: -400
main_q = [1, 2, 4, -4, 100, -40, -400, 90]
min_q = [-400, 90]
==========
Removed 1 ; Min is: -400
main_q = [2, 4, -4, 100, -40, -400, 90]
min_q = [-400, 90]
==========
Removed 2 ; Min is: -400
main_q = [4, -4, 100, -40, -400, 90]
min_q = [-400, 90]
==========
Removed 4 ; Min is: -400
main_q = [-4, 100, -40, -400, 90]
min_q = [-400, 90]
==========
Removed -4 ; Min is: -400
main_q = [100, -40, -400, 90]
min_q = [-400, 90]
==========
Removed 100 ; Min is: -400
main_q = [-40, -400, 90]
min_q = [-400, 90]
==========
Removed -40 ; Min is: -400
main_q = [-400, 90]
min_q = [-400, 90]
==========
Removed -400 ; Min is: 90
main_q = [90]
min_q = [90]
==========
exception: Queue is empty, NO minimum
Process finished with exit code 0