You only have two capturing groups in your regex:
(?:    # non-capturing group
    (  # group 1
        [0-1]?[0-9]{0,2}|2?[0-4]?[0-9]|25[0-5]?
    )\.
){3}  
(      # group 2
        [0-1]?[0-9]{0,2}|2?[0-4]?[0-9]|25[0-5]?
)
That the first group can be repeated 3 times doesn't make it capture 3 times. The regex engine will only ever return 2 groups, and the last match in a given group will fill that group.
If you want to capture each of the parts of an IP address into separate groups, you'll have to explicitly define groups for each:
pattern = (
    r'([0-1]?[0-9]{0,2}|2?[0-4]?[0-9]|25[0-5]?)\.'
    r'([0-1]?[0-9]{0,2}|2?[0-4]?[0-9]|25[0-5]?)\.'
    r'([0-1]?[0-9]{0,2}|2?[0-4]?[0-9]|25[0-5]?)\.'
    r'([0-1]?[0-9]{0,2}|2?[0-4]?[0-9]|25[0-5]?)')
def fun(st, p=re.compile(pattern)):
    return p.findall(st)
You could avoid that much repetition with a little string and list manipulation:
octet = r'([0-1]?[0-9]{0,2}|2?[0-4]?[0-9]|25[0-5]?)'
pattern = r'\.'.join([octet] * 4)
Next, the pattern will just as happily match the 25 portion of 255. Better to put matching of the 200-255 range at the start over matching smaller numbers:
octet = r'(2(?:5[0-5]|[0-4]\d)|[01]?[0-9]{1,2})'
pattern = r'\.'.join([octet] * 4)
This still allows leading 0 digits, by the way, but is 
If all you are doing is passing in single IP addresses, then re.findall() is overkill, just use p.match() (matching only at the string start) or p.search(), and return the .groups() result if there is a match;)
def fun(st, p=re.compile(pattern + '$')):
    match = p.match(st)
    return match and match.groups()
Note that no validation is done on the surrounding data, so if you are trying to extract IP addresses from a larger body of text you can't use re.match(), and can't add the $ anchor and the match could be from a larger number of octets (e.g. 22.22.22.22.22.22). You'd have to add some look-around operators for that:
# only match an IP address if there is no indication that it is part of a larger
# set of octets; no leading or trailing dot or digits
pattern = r'(?<![\.\d])' + pattern + r'(?![\.\d])'