Bellow code snippet showing my scenario:
[Table("User")]
public partial class UserModel
{
 public UserModel()
 {
    UserRole = new HashSet<UserRoleModel>();
 }
  public int UserID { get; set; }
  public string FullName { get; set; }
  public virtual ICollection<UserRoleModel> UserRole { get; set; }
}
[Table("UserRole")]
public partial class UserRoleModel
{
    public UserRoleModel()
    {
            User = new HashSet<UserModel>();
    }
   public int RoleID { get; set; }
   public string RoleName { get; set; }
   public virtual ICollection<UserModel> User { get; set; }
}
Now within OnModelCreating(DbModelBuilder modelBuilder) EF Generate code like bellow
modelBuilder.Entity<UserModel>()
                .HasMany(e => e.UserRole)
                .WithMany(e => e.User)
                .Map(m => m.ToTable("UserRoleMapping").MapLeftKey("UserID").MapRightKey("UserRoleID"));
now this is fine add / insert data into UserRoleMapping table. But how to 
Get / Update data from UserRoleMapping table ?
I try to solve this issue following create-code-first-many-to-many the post and come-up with third class with join entity 
 public partial class UserRoleMappingModel
    {
        [Key, Column(Order = 0)]
        public Guid UserId { get; set; }
        public UserModel User { get; set; }
        [Key, Column(Order = 1)]
        public int RoleId { get; set; }
        public UserRoleModel UserRole { get; set; }
    }
then add public virtual ICollection<UserRoleMappingModel> UserRoleMapping { get; set; } in both the UserModel and UserRoleModel class
But when I try to GET value from database using bellow code
var results = _userRepository.GetAll()
                 .Include(r => r.UserRoleMapping
                 .Select(s => s.UserRole))
                 .SingleOrDefault(e => e.ID == id); 
It throws ERROR
"An error occurred while executing the command definition. See the inner exception for details.System.Data.SqlClient.SqlException (0x80131904): Invalid object name 'dbo.UserRoleMappingModel'.\r\n
Even I tried bellow Configuration within OnModelCreating, but nothing work as expected
modelBuilder.Entity<UserRoleMappingModel>()
 .HasKey(e => new { e.UserId, e.RoleId });
 
    