string devicePath = @"\Device\HarddiskVolume4\Windows\System32\RuntimeBroker.exe";
string driveLetterPath = DevicePathMapper.FromDevicePath(devicePath);
// driveLetterPath == C:\Windows\System32\RuntimeBroker.exe
Since we want a path with a drive letter we need to replace \Device\HarddiskVolume4 with the correct drive letter, e.g. C:. For that use QueryDosDevice and map a dos device to each drive letter. Then we can search and replace for the dos device path.
This is a possible implementation. It uses extension methods internal:
public static class DevicePathMapper {
    [DllImport("Kernel32.dll", CharSet = CharSet.Unicode)]
    private static extern uint QueryDosDevice([In] string lpDeviceName, [Out] StringBuilder lpTargetPath, [In] int ucchMax);
    public static string FromDevicePath(string devicePath) {
        var drive = Array.Find(DriveInfo.GetDrives(), d => devicePath.StartsWith(d.GetDevicePath(), StringComparison.InvariantCultureIgnoreCase));
        return drive != null ?
            devicePath.ReplaceFirst(drive.GetDevicePath(), drive.GetDriveLetter()) :
            null;
    }
    private static string GetDevicePath(this DriveInfo driveInfo) {
        var devicePathBuilder = new StringBuilder(128);
        return QueryDosDevice(driveInfo.GetDriveLetter(), devicePathBuilder, devicePathBuilder.Capacity + 1) != 0 ?
            devicePathBuilder.ToString() :
            null;
    }
    private static string GetDriveLetter(this DriveInfo driveInfo) {
        return driveInfo.Name.Substring(0, 2);
    }
    private static string ReplaceFirst(this string text, string search, string replace) {
        int pos = text.IndexOf(search);
        if (pos < 0) {
            return text;
        }
        return text.Substring(0, pos) + replace + text.Substring(pos + search.Length);
    }
}