In the .spec a %define macro would get you the username. Here is an example, how it might look like inside the .spec file.
Source0: %{name}-%{version}.tar.gz
# User defined function to get who built the RPM
%define packagername %(who am i | awk '{print $1}')
%description
...
%prep
...
# Then in the post section call the macro %{packagername}
%post
echo "Packager is: %{packagername}"
Note, %post section will be run only when install the .rpm file. Above will print the information into stdout.
Output
$ sudo rpm -ivh simple-0-1.x86_64.rpm
Preparing... ########################################### [100%]
1:simple ########################################### [100%]
Packager is: iamauser
In order to use this macro globally on the system, one can define it inside /etc/rpm/macros.<somename>.
$ cat /etc/rpm/macros.username
# Get who is the packager
%packagername %(who am i | awk '{print $1}')
With the global definition one doesn't need to define it inside the .spec file.
If you don't have permission to write into /etc/rpm, then defining it in ~/.rpmmacros file would make that macro available only to you.