Make Sure Procfile should not have any extension like .txt
otherwise this will be the error
remote: -----> Discovering process types
 remote:        Procfile declares types -> (none)
To create file without extension type following in cmd 
 notepad Procfile.
Now add web: gunicorn dep:app and save
Now when you will git push heroku master the above lines will be like
remote: -----> Discovering process types
 remote:        Procfile declares types -> web
And the error is gone when you will run
C:\Users\Super-Singh\PycharmProjects\URLShortener>heroku ps:scale web=1
Scaling dynos... done, now running web at 1:Free