As @Lemix said in comment, sql.get is an async function and the console.log would be executed before it is done.
Also be aware of the variable scope. var UserMurderCoins is defined inside a then function and is accessed out of the scope. So, it wouldn't be defined even if the statement was executed after the sql.get.then.
you can either run the console.log inside the then function or define the variable globally and only assign it inside the then function.
UPDATE:
To be more comfortable with promises, you can use async await syntax.
I modified your code with a little changes to be working.
async function f() {
var UserMurderCoins = (await sql.get(`SELECT * FROM monney WHERE userId ="${message.author.id}"`)).coins;
console.log(UserMurderCoins);
}
f();