It's not clear what your function create()
void create(struct node * head, int num) {
  struct node * tmp = head;
  struct node * prev = NULL;
  struct node* new = malloc(sizeof(struct node));
  new->key = num;
  prev = tmp;
  tmp = tmp->next;
  while (tmp != NULL && tmp->key < num) {
      prev = tmp;
      tmp = tmp->next;
  }
  new->next = tmp;
  prev->next = new;
  if (tmp == NULL)
      head = tmp;
}
is supposed to do. You effectively pass it a NULL pointer and return void, so everything it does is meaningless to the outside world.
Thetm starting point for every no bs linked list implementation:
#include <stdbool.h>
#include <stdlib.h>
#include <stdio.h>
typedef struct node_tag {
    int value;
    struct node_tag *next;
} node_t;
// write functions to encapsulate the data and provide a stable interface:
node_t* node_create_value(int value)
{
    node_t *new_node = calloc(1, sizeof *new_node);
    if(new_node) new_node->value = value;
    return new_node;
}
node_t* node_advance(node_t const *node) { return node->next; }
typedef struct list_tag {  // a list usually consists of
    node_t *head;          // a pointer to the first and
    node_t *tail;          // a pointer to the last element
    // size_t size;        // one might want to add that.
} list_t;
list_t list_create(void)
{
    list_t list = { NULL, NULL };
    return list;
}
// make code based on these functions "speak" for itself:
node_t* list_begin(list_t const *list) { return list->head; }
node_t* list_end  (list_t const *list) { return list->tail; }
bool list_is_empty(list_t const *list) { return !list_begin(list); }
// common operations for lists:
node_t* list_push_front(list_t *list, int value)
{
    node_t *new_node = node_create_value(value);
    if (!new_node)
        return NULL;
    new_node->next = list->head;
    return list->head = new_node;
}
node_t* list_push_back(list_t *list, int value)
{
    // push_back on an empty list is push_front:
    if (list_is_empty(list))
        return list->tail = list_push_front(list, value);
    node_t *new_node = node_create_value(value);
    if (!new_node)
        return NULL;
    list->tail->next = new_node;
    return list->tail = new_node;
}
node_t* list_insert_after(list_t *list, node_t *node, int value)
{
    if (list_end(list) == node)
        return list_push_back(list, value);
    node_t *new_node = node_create_value(value);
    if (!new_node)
        return NULL;
    new_node->next = node->next;
    return node->next = new_node;
}
node_t* list_insert_sorted(list_t *list, int value)
{
    // first handle the special cases that don't require iterating the whole list:
    if (list_is_empty(list) || value < list_begin(list)->value)
        return list_push_front(list, value);
    if (value > list_end(list)->value)
        return list_push_back(list, value);
    // the general (worst) case:
    for (node_t *current_node = list_begin(list); node_advance(current_node); current_node = node_advance(current_node))
        if (value < node_advance(current_node)->value)
            return list_insert_after(list, current_node, value);
    return NULL; // should never happen
}
void list_print(list_t const *list)
{
    for (node_t *current_node = list_begin(list); current_node; current_node = node_advance(current_node))
        printf("%d\n", current_node->value);
}
void list_free(list_t *list)
{
    for(node_t *current_node = list_begin(list), *next_node; current_node; current_node = next_node) {
        next_node = current_node->next;
        free(current_node);
    }
}
// user code should not be required to know anything about the inner workings
// of our list:
int main(void)
{
    list_t list = list_create();
    for (int i = 1; i < 10; i += 2) {
        if (!list_push_back(&list, i)) {
            list_free(&list);
            fputs("Not enough memory :(\n\n", stderr);
            return EXIT_FAILURE;
        }
    }
    list_print(&list);
    putchar('\n');
    for (int i = 0; i < 11; i += 2) {
        if (!list_insert_sorted(&list, i)) {
            list_free(&list);
            fputs("Not enough memory :(\n\n", stderr);
            return EXIT_FAILURE;
        }
    }
    list_print(&list);
    list_free(&list);
}
Output:
1
3
5
7
9
0
1
2
3
4
5
6
7
8
9
10