Firstly, Your code is open to SQL injection related attacks. Please learn to use Prepared Statements
Now, from a query point of view, you can rather utilize JOIN to make this into a single query:
SELECT ci.* 
FROM CatalogueItems AS ci
JOIN mycart AS mc ON mc.itemID = ci.itemID 
WHERE mc.email = $email  /* $email is the input filter for email */
PHP code utilizing Prepared Statements of MySQLi library would look as follows:
$conn = new mysqli(server, dbuser, dbpw, db);
$email = $_GET['email'];
$querystring = "SELECT ci.* 
                FROM CatalogueItems AS ci
                JOIN mycart AS mc ON mc.itemID = ci.itemID 
                WHERE mc.email = ?";  // ? is the placeholder for email input
// Prepare the statement
$stmt = $conn->prepare($querystring);
// Bind the input parameters
$stmt->bind_param('s', $email);  // 's' represents string input type for email
// execute the query
$stmt->execute();
// fetch the results
$result = $stmt->get_result();
$rs = $result->fetch_array(MYSQLI_ASSOC);
// Eventually dont forget to close the statement
// Unless you have a similar query to be executed, for eg, inside a loop
$stmt->close();