In C you would use sscanf() or more directly, fscanf() but those functions are considered poor style in C++.  
I'd suggest something like this:
struct SData 
{
    std::string sName;
    std::string sGender;
    int nDay;
    int nMon;
    int nYear;
    int nHour;
    int nMin;
    int nSec;
};
bool ReadRecord(std::istream &istr, SData &data)
{
    istr >> data.sName
         >> data.sGender
         >> data.nDay;
    istr.ignore(1);       // '/'
    istr >> data.nMon;
    istr.ignore(1);       // '/'
    istr >> data.nYear
         >> data.nHour;
    istr.ignore(1);       // ':'
    istr >> data.nMin;
    istr.ignore(1);       // ':'
    istr >> data.nSec;
    return istr.good();
}
Update
The following example simplifies use by excluding the struct
#include <iostream>
#include <fstream>
#include <string>
bool ReadRecord(std::istream &istr, 
                std::string &sName,
                std::string &sGender,
                int &nDay,
                int &nMon,
                int &nYear,
                int &nHour,
                int &nMin,
                int &nSec)
{
    istr >> sName
         >> sGender
         >> nDay;
    istr.ignore(1); // '/'
    istr >> nMon;
    istr.ignore(1); // '/'
    istr >> nYear
         >> nHour;
    istr.ignore(1); // ':'
    istr >> nMin;
    istr.ignore(1); // ':'
    istr >> nSec;
    return istr.good();
}
int main()
{
    std::string sName0, sGender0, sName1, sGender1;
    int nDay0, nMon0, nYear0, nDay1, nMon1, nYear1;
    int nHour0, nMin0, nSec0, nHour1, nMin1, nSec1;
    const char szFileName[] = "MyData.txt";
    std::ifstream istr(szFileName);
    if (!istr.is_open())
    {
        std::cerr << "Cannot open file\n";
        return 1;
    }
    if (!ReadRecord(istr, sName0, sGender0, nDay0, nMon0, nYear0, nHour0, nMin0, nSec0))
    {
        std::cerr << "Cannot read file\n";
        return 1;
    }
    if (!ReadRecord(istr, sName1, sGender1, nDay1, nMon1, nYear1, nHour1, nMin1, nSec1))
    {
        std::cerr << "Cannot read file\n";
        return 1;
    }
    std::string sYounger;
    if (nYear0 == nYear1)
    {
        if (nMon0 == nMon1)
        {
            if (nDay0 == nDay1)
            {
                if (nHour0 == nHour1)
                {
                    if (nMin0 == nMin1)
                    {
                        if (nSec0 > nSec1)
                        {
                            sYounger = sName0;
                        }
                        else if (nSec0 < nSec1)
                        {
                            sYounger = sName1;
                        }
                    } 
                    else if (nMin0 > nMin1)
                    {
                        sYounger = sName0;
                    }
                    else if (nMin0 < nMin1)
                    {
                        sYounger = sName1;
                    }
                }
                else if (nHour0 > nHour1)
                {
                    sYounger = sName0;
                }
                else if (nHour0 < nHour1)
                {
                    sYounger = sName1;
                }
            }
            else if (nDay0 > nDay1)
            {
                sYounger = sName0;
            }
            else if (nDay0 < nDay1)
            {
                sYounger = sName1;
            }
        }
        else if (nMon0 > nMon1)
        {
            sYounger = sName0;
        }
        else if (nMon0 < nMon1)
        {
            sYounger = sName1;
        }
    }
    else if (nYear0 > nYear1)
    {
        sYounger = sName0;
    }
    else if (nYear0 < nYear1)
    {
        sYounger = sName1;
    }
    if (sYounger.empty())
    {
        std::cout << "The ages are the same\n";
    }
    else
    {
        std::cout << sYounger << "is younger\n";
    }
    return 0;
}