This is used to allow you to use reserved words as identifiers such as class names, delegates and methods. For example: long:
namespace ConsoleApp4
{
    internal class Program
    {
        private static void Main(string[] args)
        {
            @long();
        }
        public static void @long ()
        {
            // Some logic here
        }
    }
}
Remove the @ and it won't compile. It isn't often used.
Note that the code will compile fine if you change both long to long2 and remove the second @. So the use of @ means you can call a method name that is a reserved word - but it will also work if the method name is not a reserved word.
Note that the @ prefix does not form part of the identifier itself. So @myVariable is the same as myVariable.