I realize I am a Johnny-Come-Lately here, but I was working with the VERY same problem -- and the tutorials I found out there would almost (but not quite upon unit testing) cover it.
After much frustration and research, here is what I cam up with 
XML To Assoc. Array:
From http://www.php.net/manual/en/simplexml.examples-basic.php
json_decode( json_encode( simplexml_load_string( $string ) ), TRUE );
Assoc. Array to XML
notes: 
- XML attributes are not handled
- Will also handle nested arrays with numeric indices (which are not valid XML!) 
From http://www.devexp.eu/2009/04/11/php-domdocument-convert-array-to-xml/
/// Converts an array to XML
/// - http://www.devexp.eu/2009/04/11/php-domdocument-convert-array-to-xml/
/// @param  <array> $array  The associative array you want to convert; nested numeric indices are OK!
function   getXml( array $array )  {
    $array2XmlConverter  = new XmlDomConstructor('1.0', 'utf-8');
    $array2XmlConverter->xmlStandalone   = TRUE;
    $array2XmlConverter->formatOutput    = TRUE;
    try {
        $array2XmlConverter->fromMixed( $array );
        $array2XmlConverter->normalizeDocument ();
        $xml    = $array2XmlConverter->saveXML();
//        echo "\n\n-----vvv start returned xml vvv-----\n";
//        print_r( $xml );
//        echo "\n------^^^ end returned xml ^^^----\n"
        return  $xml;
    }
    catch( Exception $ex )  {
//        echo "\n\n-----vvv Rut-roh Raggy! vvv-----\n";
//        print_r( $ex->getCode() );     echo "\n";
//        print_r( $->getMessage() );
//        var_dump( $ex );
//        echo "\n------^^^ end Rut-roh Raggy! ^^^----\n"
        return  $ex;
    }
}
... and here is the class to use for the $array2XmlConverter object:
/**
 * Extends the DOMDocument to implement personal (utility) methods.
 * - From: http://www.devexp.eu/2009/04/11/php-domdocument-convert-array-to-xml/
 * - `parent::` See http://www.php.net/manual/en/class.domdocument.php
 *
 * @throws   DOMException   http://www.php.net/manual/en/class.domexception.php
 *
 * @author Toni Van de Voorde
 */
class   XmlDomConstructor   extends DOMDocument {
    /**
     * Constructs elements and texts from an array or string.
     * The array can contain an element's name in the index part
     * and an element's text in the value part.
     *
     * It can also creates an xml with the same element tagName on the same
     * level.
     *
     * ex:
        \verbatim
             <nodes>
                <node>text</node>
                <node>
                    <field>hello</field>
                    <field>world</field>
                </node>
             </nodes>
        \verbatim
     *
     *
     * Array should then look like:
        \verbatim
             array(
                "nodes" => array(
                    "node" => array(
                        0 => "text",
                        1 => array(
                            "field" => array (
                                0 => "hello",
                                1 => "world",
                            ),
                        ),
                    ),
                ),
             );
        \endverbatim
     *
     * @param mixed $mixed An array or string.
     *
     * @param DOMElement[optional] $domElement Then element
     * from where the array will be construct to.
     *
     */
    public  function    fromMixed($mixed, DOMElement $domElement = null) {
        $domElement = is_null($domElement) ? $this : $domElement;
        if (is_array($mixed)) {
            foreach( $mixed as $index => $mixedElement ) {
                if ( is_int($index) ) {
                    if ( $index == 0 ) {
                        $node = $domElement;
                    } 
                    else {
                        $node = $this->createElement($domElement->tagName);
                        $domElement->parentNode->appendChild($node);
                    }
                }
                else {
                    $node = $this->createElement($index);
                    $domElement->appendChild($node);
                }
                $this->fromMixed($mixedElement, $node);
            }
        } 
        else {
            $domElement->appendChild($this->createTextNode($mixed));
        }
    }
} // end of class