WPF
You can use an Extension method like this and call it from OnLoaded
 public static void MaximizeToSecondaryMonitor(this Window window)
        {
            var secondaryScreen = System.Windows.Forms.Screen.AllScreens.Where(s => !s.Primary).FirstOrDefault();
            if (secondaryScreen != null)
            {
                if (!window.IsLoaded)
                    window.WindowStartupLocation = WindowStartupLocation.Manual;
                var workingArea = secondaryScreen.WorkingArea;
                window.Left = workingArea.Left;
                window.Top = workingArea.Top;
                window.Width = workingArea.Width;
                window.Height = workingArea.Height;
                // If window isn't loaded then maxmizing will result in the window displaying on the primary monitor
                if ( window.IsLoaded )
                    window.WindowState = WindowState.Maximized;
            }
        }
WinForms
 private void Form1_Load(object sender, EventArgs e)
 {
        this.StartPosition = FormStartPosition.Manual;
        this.WindowState = FormWindowState.Normal;
        this.FormBorderStyle = FormBorderStyle.None;
        this.Bounds = GetSecondaryScreen().Bounds;
        this.SetBounds(this.Bounds.X , this.Bounds.Y, this.Bounds.Width, this.Bounds.Height);
 }
 private Screen GetSecondaryScreen()
 {
        foreach (Screen screen in Screen.AllScreens)
        {
            if (screen != Screen.PrimaryScreen)
                return screen;
        }
        return Screen.PrimaryScreen;
 }