A is an aggregate type, because it doesn't have any user-provided constructors (and fulfills a few other requirements).
Therefore A aa = {}; does not call the implicitly generated default constructor. Instead initialization with brace-enclosed initializer lists performs aggregate initialization, which for an empty list means that the members are initialized as if by a {} initializer, which in turn means for a member of scalar type such as int that it will be initialized to zero.
B is not an aggregate type, because it does have a user-provided constructor.
Therefore B bb = {}; cannot do aggregate initialization and will call the default constructor instead. The default constructor (in either A or B) does not specify an initializer for the members and so the member is default-initialized, which for a fundamental type, such as int, means that it will not be set to any value. Its value will remain indeterminate.
Accessing the indeterminate value, which your program does, causes undefined behavior.
If you declare a constructor yourself, then it becomes that constructor's responsibility to initialize all the members appropriately. The rule that = {} or {} always initializes only holds under the assumption that a user-provided default constructor, if it exists, does the right thing in the sense that it provides sensible initializers to all its members and it doesn't have to mean zero-initialization necessarily.