This is because the image is not loaded at the time of log. You need to console.log inside onload function
function popUp() {
  var img = document.createElement('img');
  img.id="TT";
  img.src="https://picsum.photos/200/300";    
  document.body.appendChild(img);
  img.onload = function(){
    var img = document.getElementById("TT");
    var dims = img.getBoundingClientRect();
    console.log(dims)
  }
}
popUp();
 
 
If you want the function to await for further execution of the function until the image is loaded you can create a promise and then await for it. But this will make the structure of the code asynchronous
async function popUp() {
  var img = document.createElement('img');
  img.id="TT";
  img.src="https://picsum.photos/200/300";    
  document.body.appendChild(img);
  const imageLoaded = new Promise((res, rej) => {
    img.onload = function(){
      var img = document.getElementById("TT");
      var dims = img.getBoundingClientRect();
      res(dims)
    }
  });
  
  const data = await imageLoaded;
  console.log(data)
 
}
popUp();