Premise
It is hard to analyze this without any additional input how nums and target correspond to each other.
Since you do not provide any additional information here, I have to assume that all inputs are possible. In which case the worst case is that none of the pairs buildable by nums can form target at all.
A simple example explaining what I am referring to would be target = 2 with nums = [4, 5, 10, 3, 9]. You can not build target by adding up pairs of nums.
Iterations
So you would end up never hitting your break statement, going through the full execution of the algorithm.
That is, the full range of k from 0 to nums.length - 1, then one increment of i and then k again the full range, starting from i. And so on until i reaches the end as well.
In total, you will thus have the following amount of iterations (where n denotes nums.length):
n, n - 1, n - 2, n - 3, ..., 2, 1
Summed up, those are exactly
(n^2 + n) / 2
iterations.
Complexity
Since all you do inside the iterations is in constant time O(1), the Big-O complexity of your algorithm is given by
(n^2 + n) / 2 <= n^2 + n <= n^2 + n^2 <= 2n^2
Which by definition is in O(n^2).
Alternative code
Your code is very hard to read and a rather unusual way to express what you are doing here (namely forming all pairs, leaving out duplicates). I would suggest rewriting your code like that:
for (int i = 0; i < nums.length; i++) {
    for (int j = i; j < nums.length; j++) {
        int first = nums[i];
        int second = nums[j];
        if (first + second == target) {
            return {i, j};
        }
    }
}
return null;
Also, do yourself a favor and do not return result filled with 0 in case you did not find any hit. Either return null as shown or use Optional, for example:
return Optional.of(...);
...
return Optional.empty();