I have a dataframe called 'df':
  Value   Num
0 alpha     5
1 bravo     6
2 charlie   7
And a Series called 'series_to_add':
  New Value
0 alpha     
1 bravo     
2 delta
How can I combine the unique values of the series into the existing dataframe to get something like this:
  Value   Num
0 alpha     5
1 bravo     6
2 charlie   7
3 delta     nan
 
    