If you just want to filter out the added times, you can do what cs95 said in the comments or:
out = data.groupby(pd.Grouper(freq='1h')).sum(min_count=1).dropna()
The min_count makes NaN be the output if there is no data for the bin, which can then be removed with dropna().
If you instead don't want those extra bins to be computed in the first place, this can be more complicated (Note that there is a similar open post on this, also from today). But given an hourly bin frequency, you can do something like this:
out1 = data.groupby(data.index.hour).sum()
And if the data span multiple days, you could do:
out2 = data.groupby([data.index.date, data.index.hour]).sum()
But note here that the data index is out of datetime format now, so you might need to convert back.
Here's the example data I used:
import pandas as pd
dr = pd.date_range('1-1-2020 7:00', periods=6, freq='30min')
data = pd.DataFrame([10,20,30,40,50,60], index=dr, columns=['Values'])
data = data[data.index.hour != 8]