Older versions of the puppet language have no support for loops. 
But you can use an array instead of a simple string for the title and declare several resources at the same time with the same params:
$b = '/opt/app'
file { [ "$b/app1", "$b/app2" ]:
  ensure => directory,
  owner  => 'root',
  group  => 'root',
  mode   => 0644,
}
You can also declare many resources of the same type with different params by ending each resource with a ;, which is a bit more compact than repeating the file and the {s and }s:
file {
  [ "$b/app1", "$b/app2" ]:
    ensure => directory,
    owner  => 'root',
    group  => 'root',
    mode   => 0755;
  [ "$b/app1/secret", "$b/app2/secret" ]:
    ensure => directory,
    owner  => 'root',
    group  => 'root',
    mode   => 0700;
}
In the specific case of files, you can set up a source and use recursion:
file { "/opt/app":
  source => "puppet:///appsmodule/appsdir",
  recurse => true;
}
(that would require having a source of that directory structure for puppet to use as the source)
You can define a new resource type to reuse a portion of the param multiple times:
define foo {
  file {
    "/tmp/app/${title}":
      ensure => directory,
      owner  => 'root',
      mode   => 0755;
    "/tmp/otherapp/${title}":
      ensure => link,
      target => "/tmp/app/${title}",
      require => File["/tmp/app/${title}"]
  }
}
foo { ["app1", "app2", "app3", "app4"]: } 
Starting with Puppet 2.6, there's a Ruby DSL available that has all the looping functionality you could ask for: http://www.puppetlabs.com/blog/ruby-dsl/ (I've never used it, however). In Puppet 3.2, they introduced some experimental loops, however those features may change or go away in later releases.