I found that you can swap the NSSplitView from the old-style one to the new-style one inside awakeFromNib. A sample code follows.
I assumed window and oldSplitView are IBOutlet to corresponding objects within XIB, and two dummy NSViewControllers leftVC and rightVC are created within XIB whose views are connected to the left pane and right pane. Then all you have to do is:
// enable scrolling behind the tool bar, if you haven't
window.styleMask|=NSWindowStyleMaskFullSizeContentView;
// create a new-style NSSplitView using NSSplitViewController
splitVC=[[NSSplitViewController alloc] init];
splitVC.splitView.vertical=YES;
splitVC.view.translatesAutoresizingMaskIntoConstraints=NO;
// prepare the left pane as a sidebar
NSSplitViewItem*a=[NSSplitViewItem sidebarWithViewController:leftVC];
[splitVC addSplitViewItem:a];
a.canCollapse=NO;
// prepare the right pane
NSSplitViewItem*b=[NSSplitViewItem splitViewItemWithViewController:rightVC];
[splitVC addSplitViewItem:b];
// swap the old NSSplitView with the new one
[window.contentView replaceSubview:oldSplitView with:splitVC.view ];
// set up the constraints so that the new `NSSplitView` to fill the window
[splitVC.view.topAnchor constraintEqualToAnchor:window.contentView.topAnchor
constant:0].active=YES;
[splitVC.view.bottomAnchor constraintEqualToAnchor:((NSLayoutGuide*)window.contentLayoutGuide).bottomAnchor].active=YES;
[splitVC.view.leftAnchor constraintEqualToAnchor:((NSLayoutGuide*)window.contentLayoutGuide).leftAnchor].active=YES;
[splitVC.view.rightAnchor constraintEqualToAnchor:((NSLayoutGuide*)window.contentLayoutGuide).rightAnchor].active=YES;