Try using a subquery to select the highest rated agent, then join it to your CLIENT table to select the names of the associated clients. Something like this:
SELECT ClientName
FROM CLIENT.ClientName
JOIN (
    SELECT AgentID FROM AGENT ORDER BY AgentRating DESC LIMIT 1   
) sq ON sq.AgentID = CLIENT.AgentID
The subquery (SELECT AgentID FROM AGENT ORDER BY AgentRating DESC LIMIT 1) sq selects the AgentID column from the AGENT table
Then with ORDER BY AgentRating DESC it orders that column by the AgentRating descending placing the highest rating at the top of the results.
Then the LIMIT 1 limits the rows returned to 1, giving you only 1 (the first returned) record from the AGENT table that we just ordered to put the highest rated agent at the top.
Then when you JOIN that result from the subquery with your CLIENT table on the AgentID, you will only get results in your CLIENT table maching the selected AgentID from the subquery.