It seems that you want to find the unique keys across all the dictionaries in this column. This can be done easily with functools.reduce. I've generated some sample data:
import pandas as pd
import random
possible_keys = 'abcdefg'
df = pd.DataFrame({'x': [{key: 1 for key in random.choices(possible_keys, k=3)} for _ in range(10)]})
This dataframe looks like this:
                          x
0          {'c': 1, 'a': 1}
1  {'b': 1, 'd': 1, 'c': 1}
2          {'d': 1, 'b': 1}
3  {'b': 1, 'f': 1, 'e': 1}
4  {'a': 1, 'd': 1, 'c': 1}
5          {'g': 1, 'b': 1}
6                  {'d': 1}
7                  {'e': 1}
8  {'c': 1, 'd': 1, 'f': 1}
9  {'b': 1, 'a': 1, 'f': 1}
Now the actual meat of the answer:
from functools import reduce
reduce(set.union, df['x'], set())
Results in:
{'a', 'b', 'c', 'd', 'e', 'f', 'g'}