Any integer value prefixed with 0 is an octal value. I.e.: 01 is octal 1, 010 is octal 10, which is decimal 8, and 0 is octal 0 (which is decimal, and any other, 0).
So yes, '0' is an octal.
That's plain English translation of the grammar snippet in @Als's answer :-)
An integer prefixed with 0x is not prefixed with 0. 0x is an explicitly different prefix. Apparently there are people who cannot make this distinction.
As per that same standard, if we continue:
integer-literal:
decimal-literal integer-suffixopt
octal-literal integer-suffixopt
hexadecimal-literal integer-suffixopt
decimal-literal:
nonzero-digit <<<---- That's the case of no prefix.
decimal-literal digit-separatoropt digit
octal-literal:
0 <<<---- '0' prefix defined here.
octal-literal digit-separatoropt octal-digit <<<---- No 'x' or 'X' is
allowed here.
hexadecimal-literal:
0x hexadecimal-digit <<<---- '0x' prefix defined here
0X hexadecimal-digit <<<---- And here.
hexadecimal-literal digit-separatoropt hexadecimal-digit