By default, not there is no way to do this.  Links always perform GETs, forms can use GETs or POSTs.
That said, with a little JavaScript, it's possible.  Rails for instance ships with helpers which will add a data-method attribute to links.  Rails-UJS is a jQuery library that will transparently intercept clicks on these links, and trigger a form submit with a _method parameter used for overriding the normal HTTP method.  Finally Rack will intercept requests with a _method params, and overwrite the request method with the value in _method.  
Other frameworks no doubt follow a similar pattern.
If you want even more details, I've written up an explanation of how Rails, Rails-UJS, and Rack all work together to provide this.  
It's good to know how your libraries work.