I tried in the snippet below:
a, b = a[b] = {}, 5
print('a={0},b={1}'.format(a,b))
The IDE spits out the follows:
a={5: ({...}, 5)},b=5
I have tried S3DEV's advice and execute:
from dis import dis
dis('a, b = a[b] = {}, 5')
And it gives me the follows:
  1       0 BUILD_MAP                0
          2 LOAD_CONST               0 (5)
          4 BUILD_TUPLE              2
          6 DUP_TOP
          8 UNPACK_SEQUENCE          2
         10 STORE_NAME               0 (a)
         12 STORE_NAME               1 (b)
         14 LOAD_NAME                0 (a)
         16 LOAD_NAME                1 (b)
         18 STORE_SUBSCR
         20 LOAD_CONST               1 (None)
         22 RETURN_VALUE
But I still cannot understand why a[b] = a, 5 happened in the step 18 STORE_SUBSCR. Any further explanation?
 
    