I have data frame and target value like this:
target = 'Math'
df:
Col1   Col2 
Math   Science
Music  Math
Social Math
Arts   Math
I want to create a new column(New_Col) such that 
if Col1 == target i.e Math:
    New_Col = Col2 value
else:
    New_Col = Col1 value
So the output looks like this:
df:
Col1   Col2        New_Col
Math   Science      Science
Music  Math         Music
Social Math         Social
Arts   Math         Arts
Can anyone help me with this?