I have below output
msg: '  [(''N5K'', ''5548UPQ'')] '
I've tried the following
" {{ platform_list[0] }} "
but it returns one character only and I want to extract 'N5K'.
I have below output
msg: '  [(''N5K'', ''5548UPQ'')] '
I've tried the following
" {{ platform_list[0] }} "
but it returns one character only and I want to extract 'N5K'.
As already mentioned in the comments, the output is not a list but a string.
To get a better insight into the variable type you may use according Managing data type - Discovering the data type type_debug.
- debug: 
    msg: "{{ platform_list }} of type {{ platform_list| type_debug }}"
Further Q&A
How to proceed further?
To get a better understanding you may have a look into the following Minimal, Reproducible Example
---
- hosts: localhost
  become: false
  gather_facts: false
  vars:
    LIST: ['N5K', '5548UPQ']
  tasks:
  - name: Show type
    debug:
      msg: "{{ LIST }} and of type {{ LIST | type_debug }}"
  - name: Show element
    debug:
      msg: "{{ LIST[0] }}"
resulting into an output of
TASK [Show type] *********************************
ok: [localhost] =>
  msg: '[u''N5K'', u''5548UPQ''] and of type list'
TASK [Show element] ******************************
ok: [localhost] =>
  msg: N5K
You can then change the vars in example into a string
  vars:
    STRING: "['N5K', '5548UPQ']"
  tasks:
  - name: Show type
    debug:
      msg: "{{ STRING }} and of type {{ STRING | type_debug }}"
  - name: Show element
    debug:
      msg: "{{ STRING[0] }}"
resulting into an output of
TASK [Show type] *****************************************
ok: [localhost] =>
  msg: '[''N5K'', ''5548UPQ''] and of type AnsibleUnicode'
TASK [Show element] **************************************
ok: [localhost] =>
  msg: '['
because of Python Slicing.
