This is my Web.config:
<system.net>
    <mailSettings>
        <smtp deliveryMethod="Network">
            <network defaultCredentials="true" enableSsl="true" host="smtp.gmail.com" port="25" userName="xxxxxxx@gmail.com" password="xxxxxxxxxxx"/>
        </smtp>
    </mailSettings>
</system.net>
My method:
public static void EmailVerification(string email, string nickname)
    {
        MailAddress from = new MailAddress("xxxxxxxxxxx", "xxxxxxxxxxxx");
        MailAddress to = new MailAddress(email);
        MailMessage message = new MailMessage(from, to);
        message.Subject = "Test";
        message.Body = "Test";
        SmtpClient client = new SmtpClient();
        try
        {
            client.Send(message);
        }
        catch(SmtpFailedRecipientException ex)
        {
            HttpContext.Current.Response.Write(ex.Message);
            return;
        }
    }
My failure SmtpException:
Failure sending mail.
InnerException:
Unable to connect to the remote server
I'm testing it locally but I guess it should work. I have to run it on Windows Azure, I tried and it didn't work too. Is there something I'm missing?
 
    