When you run this code, it somehow works as well as the number of characters entered by scanf after the first operation. What's the problem?
I filled in the blank space before %c because I thought it might be a buffer problem, but the error still occurs.
void EX18() {
    float x, y;
    char op;
    int i = 0;
    while (1) {
        /*
        printf("\n******************** \n");
        printf("A ---- Add \n");
        printf("S ---- Subtract \n");
        printf("M ---- Multiply \n");
        printf("D ---- Divide \n");
        printf("Q ---- Quit \n");
        printf("******************** \n");
        */
        i++;
        printf("\n%dth iteration \n",i);
        printf("Select an operation: ");
        scanf(" %c", &op);
        if (op == 'Q') break;
        else {
            switch (op) {
            case 'A':
                printf("Enter two numbers separated by a space: ");
                scanf("%f %f", &x, &y);
                printf("%.2f \n", x + y);
                break;
            case 'S':
                printf("Enter two numbers separated by a space: ");
                scanf("%f %f", &x, &y);
                printf("%.2f \n", x - y);
                break;
            case 'M':
                printf("Enter two numbers separated by a space: ");
                scanf("%f %f", &x, &y);
                printf("%.2f \n", x * y);
                break;
            case 'D':
                printf("Enter two numbers separated by a space: ");
                scanf("%f %f", &x, &y);
                printf("%.2f \n", x / y);
                break;
            default:
                printf("\nUnknown command. Please try again.\n");
            }
        }
    }
}
int main()
{
    EX18();
    //TEST5();
    return 0;
}
Result Screen :
1th iteration Select an operation: 00
Unknown command. Please try again.
2th iteration Select an operation: Unknown command. Please try again.
3th iteration Select an operation: 000
Unknown command. Please try again.
4th iteration Select an operation: Unknown command. Please try again.
5th iteration Select an operation: Unknown command. Please try again.
6th iteration Select an operation:
 
     
    