Not all properties are available in the Outlook object model. Lowl-level properties are available using the PropertyAccessor.GetProperty method which returns an Object that represents the value of the property specified by SchemaName. For getting transport headers you may use the following code:
Sub DemoPropertyAccessorGetProperty()
Dim PropName, Header As String
Dim oMail As Object
Dim oPA As Outlook.PropertyAccessor
'Get first item in the inbox
Set oMail = _
Application.Session.GetDefaultFolder(olFolderInbox).Items(1)
'PR_TRANSPORT_MESSAGE_HEADERS
PropName = "http://schemas.microsoft.com/mapi/proptag/0x007D001E"
'Obtain an instance of PropertyAccessor class
Set oPA = oMail.PropertyAccessor
'Call GetProperty
Header = oPA.GetProperty(PropName)
Debug.Print (Header)
End Sub
But in some cases you would need to use Extended MAPI for getting low-level properties because the OOM applies its own restrictions to them.