When using setSizePolicy(QSizePolicy.Expanding, QSizePolicy.Expanding) in Pyside6, QPushButtons react when expanding the window and become bigger, but QRadioButtons remain the same.
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Here the code, in case you want to give it a try:
from PySide6.QtWidgets import (
    QLabel,
    QPushButton,
    QSizePolicy,
    QHBoxLayout,
    QVBoxLayout,
    QWidget,
    QRadioButton,
    QSpacerItem
)
import sys
from PySide6.QtWidgets import QApplication
class ExampleWidget(QWidget):
    def __init__(self):
        super().__init__()
        self.button1 = QPushButton("Example1")
        self.button2 = QPushButton("Example2")
        self.button3 = QPushButton("Example3")
        self.button4 = QPushButton("Example4")
        self.button1.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        self.button2.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        self.button3.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        self.button4.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        widget_layout_buttons = QVBoxLayout()
        widget_layout_buttons.addWidget(self.button1)
        widget_layout_buttons.addWidget(self.button2)
        widget_layout_buttons.addWidget(self.button3)
        widget_layout_buttons.addWidget(self.button4)
        widget_layout_options = QVBoxLayout()
        self.selection_label = QLabel("Choose one:")
        self.selection_label.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        self.option1 = QRadioButton("Option 1")
        self.option2 = QRadioButton(
            "Option 2")
        self.option3 = QRadioButton("Option 3")
        self.option4 = QRadioButton("Option 4")
        self.option1.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        self.option2.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        self.option3.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        self.option4.setSizePolicy(
            QSizePolicy.Expanding, QSizePolicy.Expanding)
        widget_layout_options.addWidget(self.selection_label)
        widget_layout_options.addWidget(self.option1)
        widget_layout_options.addWidget(self.option2)
        widget_layout_options.addWidget(self.option3)
        widget_layout_options.addWidget(self.option4)
        merged_options_buttons = QHBoxLayout()
        merged_options_buttons.addLayout(widget_layout_buttons)
        spacer = QSpacerItem(20, 40, QSizePolicy.Expanding,
                             QSizePolicy.Expanding)
        merged_options_buttons.addItem(spacer)
        merged_options_buttons.addLayout(widget_layout_options)
        self.setLayout(merged_options_buttons)
app = QApplication(sys.argv)
window = ExampleWidget()
window.show()
app.exec()

